Close menu. Download is DRM protected. Such displays are likely to be of most use for visual exploration of the properties of the more significant transitions contributing to computed contours of large molecules. Show all volumes and issues. The tables of contents are generated automatically and are based on the data records of the individual contributions available in the index of the TIB portal. The display of the Tables of Contents may therefore be incomplete.
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Vibronic spectra involve simultaneous changes in the vibrational and electronic energy states of a molecule. In the gas phase vibronic transitions are accompanied by changes in rotational energy also. Vibronic spectra of diatomic molecules have been analysed in detail;  emission spectra are more complicated than absorption spectra. The intensity of allowed vibronic transitions is governed by the Franck—Condon principle.